Synergetic effect of Au nanoparticles and transition metal phosphides for enhanced hydrogen evolution from...

The hydrogen evolution from ammonia borane is intriguing but challenging due to its sluggish kinetics. In this regard, the gold nanoparticles amalgamation with metal phosphides is speculated to be more efficient catalysts. Here, the catalysts Au/Ni₂P and Au/CoP with the high synergetic effect of Au nanoparticles and metal phosphides were synthesized for ammonia borane hydrolysis. The activity of Au/Ni₂P increases 4.8-fold (i.e., 0.08 to 0.40 L∙h^-1) compared to pristine Ni₂P, and the activity of Au/CoP increases 1.7-fold (i.e., 0.74 to 1.27 L∙h^-1) compared to pristine CoP. This reveals that the synergetic effect of Au^δ+ and (Ni₂P) ^δ- is stronger than Au^δ+ and (CoP) ^δ- which is manifested by XPS analysis. The kinetics exposes that the activation energy of Au/Ni₂P (45.28 kJ∙mole^-1) is greater than Au/CoP (31.45 kJ∙mole^-1) and the TOF of Au/Ni₂P is less than Au/CoP. This research work presents an effective approach for producing active sites of Au^δ+ and (Ni₂P & CoP) ^δ- for ammonia borane hydrolysis to enhance the H₂ evolution rate.