Spinach-derived boron-doped g-C₃N₄/TiO₂ composites for efficient photo-degradation of methylene blue dye

Green synthesis of nanoparticles can be beneficial due to their low toxicity, cost-effectiveness, and environment-friendliness. Its synthesis involves the use of eco-friendly and biodegradable materials such as plant extracts, natural products, and microorganisms to reduce the negative environmental impacts of traditional nanoparticle synthesis methods. Herein, Spinacia oleracea leaves are used as a boron source, and a visible light active photo-catalyst is produced. The effect of Co-Catalyst Boron in Graphitic carbon nitride based nanocomposites for methylene blue dye photo-degradation in water is examined. Titanium dioxide (TiO₂) was activated by changing the hydrogen potential value while utilizing a typical orange dye as a sensitizer. The graphitic carbon nitride/TiO₂ nanocomposites were synthesized through a hydrothermal technique. To improve their performance, Boron used as a co-catalyst and B-doped g-C₃N₄/TiO₂nanocomposites prepared through wet chemical co-percipitate mathod. UV-visible spectroscopy, SEM and FTIR spectroscopy were used to analyze the photocatalyst and boron-doped composites in detail. The photocatalytic performance of pristine photocatalyst CNTx (x = 2%,4%,6%,8%) and B-doped CNTx composites were examined for Methylene Blue degradation in the presence of a light source. The spectroscopy analysis showed that B-doped g-C₃N₄/TiO₂ -8% nano-composites performed better than all other synthesized pristine catalysts and composites in this research. This research has demonstrated that B-doped g-C₃N₄/TiO₂ composites can provide an ideal solution for treating polluted water using visible light as a source to activate these photocatalysts.