Significantly enhanced photothermal catalytic CO₂ reduction over TiO₂/g-C₃N₄ composite with full spectrum solar light

Using solar energy to drive catalytic conversion of CO₂ into value-added chemicals has great potential to alleviate the global energy shortage and anthropogenic climate change. Herein, a "hitting three birds with one stone" strategy was reported to prepared boron-doped g-C₃N₄/TiO_2-x composite (BCT) by a one-step thermal reduction process. A series of characterizations showed that the composite catalyst has extended full-spectrum absorption, rapid photogenerated charge separation, and outstanding CO₂ photoreduction performance (265.2 μmol g^-1h^-1), which is 7.5 and 9.2 times higher than that of pure TiO₂ and g-C₃N₄, respectively. In addition, the CO₂ conversion rate can be further increased to 345.1 μmol g^-1h^-1 at 70 °C due to its excellent photothermal conversion. Mechanistic studies reveal that synergistic effects alter the charge density distribution, thereby lowering the energy barrier for CO₂ conversion by adsorbing and activating CO₂ molecules_. This work provides a novel three-in-one integrated strategy for fabricating high-efficiency catalysts.