Stable thallium (Tl) isotopic signature as a reliable source tracer in river sediments impacted by mining activities

Thallium (Tl) is an extremely toxic metal, whose geochemical behavior remains poorly understood. This study aims to clarify the migration pathway and source apportionment of Tl in sediments from a watershed downstream of an open and large-scale pyrite mine area in south China, using high-precised Tl isotopic compositions. Results showed that Tl isotopic fractionations were mainly influenced by the anthropogenic Tl sources in all the sediments as a whole from the studied watershed, while in situ mineral adsorption and biological activity were limited. Moreover, plot of ε²⁰⁵Tl vs. 1/Tl further illustrated that three possible end-members, viz. background sediments, pyrite tailings, and sewage treatment wastes were ascribed to predominant sources of Tl enrichment in the sediments. A ternary mixing model unveiled that waste from pyrite mining activities (i.e., both pyrite tailings and sewage treatment wastes) affected the downstream sediments up to 10 km. All these findings suggest that Tl isotopic signature is a reliable tool to trace Tl sources in the sediments impacted by mining activities. It is highly critical for further target-oriented and precise remediation of Tl contamination.