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Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
A novel supramolecular Zn(ii)-metallogel: an efficient microelectronic semiconducting device application
Kripasindhu Karmakar1, Arka Dey2, Subhendu Dhibar1
1Colloid Chemistry Laboratory, Department of Chemistry, The University of Burdwan Golapbag Burdwan-713104 West Bengal India sdhibar@scholar.buruniv.ac.in bsaha@chem.buruniv.ac.in +91 7001575909 +91 9476341691.
Abstract:
A unique strategy for the synthesis of a supramolecular metallogel employing zinc ions and adipic acid in DMF medium has been established at room temperature. Rheological analysis was used to investigate the mechanical characteristics of the supramolecular Zn(ii)-metallogel. Field emission scanning electron microscopy and transmission electron microscopy were used to analyse the hexagonal shape morphological features of the Zn(ii)-metallogel. Interestingly, the electrical conductivity is observed in the electronic device with Zn(ii)-metallogel based metal-semiconductor (MS) junctions. All aspects of the metallogel's electrical properties were investigated. The electrical conductivity of the metallogel-based thin film device was 7.38 × 10-5 S m-1. The synthesised Zn(ii)-metallogel based device was investigated for its semi-conductive properties, such as its Schottky barrier diode nature.
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