The effect of Er³⁺ concentration on the kinetics of multiband upconversion in NaYF₄:Yb/Er microcrystals

In Yb-Er co-doped upconversion (UC) nanomaterials, upconversion luminescence (UCL) can be modulated to generate multiband UCL emissions by changing the concentration of activator Er³⁺. Nonetheless, the effect of the Er³⁺ concentrations on the kinetics of these emissions is still unknown. We here study the single β-NaYF₄:Yb³⁺/Er³⁺ microcrystal (MC) doped with different Er³⁺ concentrations by nanosecond time-resolved spectroscopy. Interestingly, different Er³⁺ doping concentrations exhibit different UCL emission bands and UCL response rates. At low Er³⁺ doping concentrations (1 mol%), multiband emission in β-NaYF₄:Yb³⁺/Er³⁺ (20/1 mol%) MCs could not be observed and the response rate of UCL was slow (5-10 μs) in β-NaYF₄:Yb³⁺/Er³⁺. Increasing the Er³⁺ doping concentration to 10 mol% can shorten the distance between Yb³⁺ ions and Er³⁺ ions, which promotes the energy transfer between them. β-NaYF₄:Yb³⁺/Er³⁺ (20/10 mol%) can achieve obvious multiband UCL and a quick response rate (0.3 µs). However, a further increase in the Er doping concentration (80 mol%) makes MCs limited by the CR process and cannot achieve the four-photon UC process (⁴F_5/2 → ²K_13/2 and ²H_9/2 → ²D_5/2). Therefore, the result shows that changing the Er³⁺ doping concentration could control the energy flow between the different energy levels in Er³⁺, which could affect the response time and UCL emission of the Yb/Er doped rare earth materials. Our work can facilitate the development of fast-response optoelectronics, optical-sensing, and display industries.