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Optochemical control of Cu(I) homeostasis in mammalian cells

Pritam Kumar Pain1, Dipanwita Palit1, Meenakshi Shegane1

  • 1Department of Chemistry, Indian Institute of Science Education and Research Bhopal, Bhopal Bypass Road, Bhauri, Bhopal-462066, MP, India. dmanna@iiserb.ac.in.

Chemical Communications (Cambridge, England)
|February 7, 2023
PubMed

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Metal ions can be separated from one another by complexation with organic ligands–the chelating agent– to form uncharged chelates. Here, the chelating agent must contain hydrophobic groups and behave as a weak acid, losing a proton to bind with the metal. Since most organic ligands used in this process are insoluble or undergo oxidation in the aqueous phase, the chelating agent is initially added to the organic phase and extracted into the aqueous phase. The metal-ligand complex is...
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