Recent advances in new generation nanocomposite materials for adsorption of pharmaceuticals from aqueous environment

With rapid increase in the human population, a large amount of wastewater is generated every year. The availability of fresh water is decreasing at an alarming rate due to rapid industrialization and agricultural development. Pharmaceutical drugs which are credited for improving standards of life worldwide have emerged as major water contaminants, raising global concern about their potential risk to human health and environment. The presence of pharmaceutical compounds is detected in surface water (sea, river, lakes, etc.), groundwater, effluents from municipal, hospitals, and wastewater treatment plants, and even in drinking water. Efficient removal of pharmaceutical pollutants still remains a challenging task. Many techniques, including photodegradation, photocatalysis, oxidation, reverse osmosis, biodegradation, nanofiltration, adsorption, etc., have been used for the remediation of wastewater. Adsorption of pharmaceutical compounds on nanoadsorbents, as a low-cost and feasible technology, has gained immense popularity for wastewater treatment over the last decade. Adsorption techniques can be integrated with wastewater treatment plants to achieve efficient removal on an industrial level. Herein, we review the literature on the remediation techniques used for the pharmaceutical waste treatment using carbon nanotubes, metal oxides, nanoclay, and new-generation MXenes via adsorption. These materials show excellent adsorptive properties owing to their high surface area, low cost, high porosity, easy functionalization, and high surface reactivity. The adsorption mechanism of the nanoadsorbents and their reusability as a factor of sustainability have also been included in the review. The factors affecting the adsorption, including pH, the concentration of adsorbate, ionic strength, and adsorbate dose, have also been discussed.