One-step fabrication of Cu-doped Bi₂MoO₆ microflower for enhancing performance in photocatalytic nitrogen fixation

This study enhances the photocatalytic N₂ immobilization performance of Bi₂MoO₆ through Cu doping. Cu-doped Bi₂MoO₆ was synthesized via a simple solvothermal method. Various characterizations were implemented to examine the influence of Cu doping on the properties of Bi₂MoO₆. Results indicated that the doped Cu element had a valence state of + 2 and substituted the position of Bi³⁺. Cu doping exerted minimal effect on the morphology of Bi₂MoO₆ but largely influenced the energy band structure. The band gap was slightly narrowed, and the conduction band was raised, such that Cu-doped Bi₂MoO₆ could generate more electrons with stronger reducibility. Moreover, importantly, Cu doping reduced work function and improved charge separation efficiency, which was considered the major cause of enhanced photoactivity. In addition, the Cu-Bi₂MoO₆ catalyst exhibited higher capability in the adsorption and activation of N₂. Under the combined effects of the aforementioned changes, Cu-Bi₂MoO₆ demonstrated considerably higher photocatalytic efficiency than Bi₂MoO₆. The optimized NH₃ generation rate reached 302 μmol/L g^-1h^-1 and 157 μmol/L g^-1h^-1 under simulated solar light and visible light, respectively, both achieving about 2.2 times higher than that of Bi₂MoO₆. This work provides a successful example of improving photocatalytic N₂ fixation, and it may show some light on the design and preparation of heteroatom-doped semiconductor photocatalysts for N₂-to-NH₃ conversion.