A new strategy for treating Pb²⁺ and Zn²⁺ pollution with industrial waste derivatives Humin

Metal pollution caused by industrial waste accumulation is a long-term and far-reaching problem. Humin (HM), as a highly condensed organic component insoluble in alkaline or water solution, is often discarded as humic acid industrial waste. However, the abundant active functional groups in HM reported by some researches make it possible for HM to remove metals. In this study, a waste reuse strategy was proposed to reduce the pressure of industrial metal pollution on the environment. HM was obtained from lignite waste residue. Scanning electron microscopy, energy spectrum and Fourier infrared spectroscopy, combined with the adsorption models were employed to reveal the mechanism of HM adsorption. The results showed that HM had multiple adsorption mechanism and high biological stability. The adsorption capacity of HM to Zn²⁺ and Pb²⁺ were 194.88 mg/g and 289.59 mg/g respectively. HM adsorbed Zn²⁺ mainly by physical multilayer adsorption. And the adsorption of Pb²⁺ by HM was mainly a monolayer chemical reaction, which depended on its active functional groups and the exchange of valence electrons. Notably, HM could simultaneously remove Pb²⁺ and Zn²⁺ and almost did not affect its original adsorption capacity to single ions. These results will provide a new strategy for the treatment of metal pollution in the future and alleviate the pressure of multiple metal pollution of the environment.