Maxwellianization of Positrons Cooling in CF_{4} and N_{2} Gases

Positron cooling in CF_{4} and N_{2} gases via inelastic vibrational and rotational (de)excitations is simulated, importantly including elastic positron-positron collisions. For CF_{4}, it is shown that rotational (de)excitations play no role on the experimental timescale, and further, that in the absence of positron-positron collisions, cooling via excitation of the dipole-active ν_{3} and ν_{4} modes alone would lead to a non-Maxwellian positron momentum distribution, in contrast to the observations of experiment. It is shown that the observed Maxwellianization of the distribution may be effected by positron-positron collisions and/or cooling involving the combination of the dipole-inactive ν_{1} mode with the dipole-active modes. For N_{2}, rotational excitations alone are sufficient to Maxwellianize the distribution (vibrational effects are negligible).