Tungsten disulfide (WS₂) is a highly active co-catalyst in Fe(III)/H₂O₂ Fenton-like reactions for efficient...

The most important factor that restricts the decomposition of H₂O₂ in the Fe³⁺/H₂O₂ reaction is the slow cycling efficiency of reducing Fe³⁺ to Fe²⁺. In this study, the addition of tungsten disulfide (WS₂) as a co-catalyst achieved a rapid cycling of the reaction rate-limiting step and a significant enhancement of H₂O₂ decomposition, which resulted in the effective degradation of acetaminophen (APAP). Results show that 99.6% of APAP (5 mg L^-1) could be degraded by H₂O₂/Fe³⁺/WS₂ system within 2.5 min. The conversion of Fe³⁺ to Fe²⁺ occurred mainly on the surface of WS₂ due to the redox reaction of the exposed W⁴⁺ active sites with Fe³⁺ after the unsaturated S atoms were bound to protons. Electron paramagnetic resonance (EPR) and radical quenching experiments evaluated the contribution of hydroxyl radical (•OH) and superoxide radical (O₂^•-) in the degradation of pollutants. WS₂ showed good recoverability after four cycles of the reaction. This study provides a new perspective to improve the efficiency of Fe³⁺/H₂O₂ and provides a reference for the involvement of transition metal sulfides in advanced oxidation processes (AOPs).