A p-n Junction by Coupling Amine-Enriched Brookite-TiO₂ Nanorods with Cu_xS Nanoparticles for Improved Photocatalytic...

Photocatalytic CO₂ reduction is a promising technology for reaching the aim of "carbon peaking and carbon neutrality", and it is crucial to design efficient photocatalysts with a rational surface and interface tailoring. Considering that amine modification on the surface of the photocatalyst could offer a favorable impact on the adsorption and activation of CO₂, in this work, amine-modified brookite TiO₂ nanorods (NH₂-B-TiO₂) coupled with Cu_xS (NH₂-B-TiO₂-Cu_xS) were effectively fabricated via a facile refluxing method. The formation of a p-n junction at the interface between the NH₂-B-TiO₂ and the Cu_xS could facilitate the separation and transfer of photogenerated carriers. Consequently, under light irradiation for 4 h, when the Cu_xS content is 16%, the maximum performance for conversion of CO₂ to CH₄ reaches at a rate of 3.34 μmol g^-1 h^-1 in the NH₂-B-TiO₂-Cu_xS composite, which is approximately 4 times greater than that of pure NH₂-B-TiO₂. It is hoped that this work could deliver an approach to construct an amine-enriched p-n junction for efficient CO₂ photoreduction.