Dual functionality luminescence thermometry with Gd₂O₂S:Eu³⁺,Nd³⁺ and its multiple applications in biosensing and in...

Luminescence thermometry using sharp line emission of lanthanide ions has become an active area of research as it offers the advantages of remote temperature sensing with high sensitivity and superior spatial resolution. The most widely applied method relies on the temperature dependence of the luminescence intensity ratio of emission lines from two thermally coupled levels. However, the usable temperature range for this type of Boltzmann thermometer is limited. In addition, the weak and narrow line absorption of the parity forbidden 4f-4f transitions of lanthanides forms a serious drawback. To solve both problems, we here report a new dual functionality luminescence thermometer: Gd₂O₂S co-doped with Eu³⁺ and Nd³⁺. This material combines Boltzmann and energy transfer thermometry to extend the temperature range and uses the strong and broad charge transfer absorption band of Eu³⁺ for sensitization. In the T-range of 300-500 K efficient energy transfer from Eu³⁺ to Nd³⁺ allows for charge transfer-sensitized luminescence thermometry using near infrared emission from the thermally coupled ⁴F_3/2 and ⁴F_5/2 levels of Nd³⁺. Above 500 K a high temperature sensitivity is obtained using the strong temperature dependence of the luminescence intensity ratio of red Eu³⁺ to near infrared Nd³⁺ emission. The dual-functionality provides a single thermometer combining strong absorption and high relative sensitivity (0.6 - 1.4%) over a wide temperature range (300 to 650 K). Finally, it is proposed that this dual-function luminescent thermometer has promising potential for multifunctional applications in biosensors and in situ temperature measurements of chemical reaction process.