Study on persulfate activated by Ce-modified tea waste biochar to degrade tetracycline

In this study, the Ce-modified tea residue biochar (Ce-TBC) was successfully generated and applied to the biochar/persulfate system (Ce-TBC/PDS), the mechanism of the removal of tetracycline (TC) using Ce-TBC/PDS was elaborated. Under the optimal experimental conditions (Ce-TBC = 0.8 g L^-1, PDS = 4 mM, TC = 10 mg L^-1), the removal efficiency of TC was 91.28%, and after 5 cycles, the elimination rate of Ce-TBC/PDS still reached up to 80%. The mechanism of TC removal by Ce-TBC/PDS was analyzed by scanning electron microscopy (SEM), X-ray diffractometer (XRD), Fourier infrared transform spectrometer (FT-IR), and X-ray photoelectron spectrometer (XPS) characterization, and influence factor experiments. The results showed that the introduction of CeO_x increased the oxygen vacancies on the TBC surface and promoted the interconversion between Ce³⁺ and Ce⁴⁺ for better activation of PDS and generation of active species. Free radical quenching experiments and paramagnetic resonance spectrometry (EPR) analysis showed that the non-radical pathway ¹O₂ played a dominant role in the Ce-TBC/PDS system. The present work provided an efficient means of PDS activator and recycling of tea waste.