Z-Scheme Modulated Charge Transfer on InVO₄ @ZnIn₂ S₄ for Durable Overall Water Splitting

The charge transfer within heterojunction is crucial for the efficiency and stability of photocatalyst for overall water splitting (OWS). Herein, InVO₄ nanosheets have been employed as a support for the lateral epitaxial growth of ZnIn₂ S₄ nanosheets to produce hierarchical InVO₄ @ZnIn₂ S₄ (InVZ) heterojunctions. The distinct branching heterostructure facilitates active site exposure and mass transfer, further boosting the participation of ZnIn₂ S₄ and InVO₄ for proton reduction and water oxidation, respectively. The unique Z-scheme modulated charge transfer, visualized by simulation and in situ analysis, has been proved to promote the spatial separation of photoexcited charges and strengthen the anti-photocorrosion capability of InVZ. The optimized InVZ heterojunction presents improved OWS (153.3 µmol h^-1  g^-1 for H₂ and 76.9 µmol h^-1  g^-1 for O₂ ) and competitive H₂ production (21090 µmol h^-1  g^-1 ). Even after 20 times (100 h) of cycle experiment, it still holds more than 88% OWS activity and a complete structure.