Luminescence Enhancement of CsMnBr₃ Nanocrystals through Heterometallic Doping

The absorption and photoluminescence (PL) of CsMnBr₃ with Mn(II) in octahedral crystal fields are extremely weak due to a d-d forbidden transition. Herein, we introduce a facile and general synthetic procedure that can prepare undoped and heterometallic doped CsMnBr₃ NCs at room temperature. Importantly, both PL and absorption of CsMnBr₃ NCs were significantly improved after doping a small amount of Pb²⁺ (4.9%). The absolute photoluminescence quantum yield (PL QY) of Pb-doped CsMnBr₃ NCs is up to 41.5%, 11-fold higher than undoped CsMnBr₃ NCs (3.7%). The PL enhancement is attributed to the synergistic effects between [MnBr₆]^4- units and [PbBr₆]^4- units. Furthermore, we verified the similar synergistic effects between [MnBr₆]^4- units and [SbBr₆]^4- units in Sb-doped CsMnBr₃ NCs. Our results highlight the potential of tailoring luminescence properties of manganese halides through heterometallic doping.