Effective removal of brilliant green with magnetic barium phosphate composites: factor analysis and mechanism study

In this work, magnetic barium phosphate (FBP) composites with different content of commercial Fe₃O₄ nanoparticles were easily prepared by a one-step hydrothermal method. FBP composites with a magnetic content of 3% (FBP3) were studied as the example for the removal of an organic pollutant (Brilliant Green, BG) from the synthetic medium. The adsorption study was executed under the variation of different experimental conditions, such as solution pH (5 ~ 11), dosage (0.02 ~ 0.20 g), temperature (293 ~ 323 K), and the contact time (0 ~ 60 min) on the removal of BG. For comparison purposes, the one-factor-at-a-time (OFAT) approach and Doehlert matrix (DM) were both employed to investigate the factor impacts involved. FBP3 showed a high adsorption capacity of 1419.3 ± 10.0 mg/g for at 25 °C and pH = 6.31. The kinetics study revealed the pseudo-second-order kinetic model as the best-fitted model, and the thermodynamic data fit well with the Langmuir model. The possible adsorption mechanisms involved are the electrostatic interaction and/or hydrogen bonding of PO₄^3-…N⁺/C-H and HSO₄^-…Ba²⁺ between FBP3 and BG. Furthermore, FBP3 showed good easy reusability and high capacities for BG removal. Our results provide new insights for developing low-cost, efficient, and reusable adsorbent to remove BG from industrial wastewater.