Interactions between H₂O₂ and dissolved organic matter during granular activated carbon-based residual H₂O₂ quenching...

Granular activated carbon (GAC) filtration can be employed to synchronously quench residual H₂O₂ from the upstream UV/H₂O₂ process and further degrade dissolved organic matter (DOM). In this study, rapid small-scale column tests (RSSCTs) were performed to clarify the mechanisms underlying the interactions between H₂O₂ and DOM during the GAC-based H₂O₂ quenching process. It was observed that GAC can catalytically decompose H₂O₂, with a long-lasting high efficiency (>80% for approximately 50,000 empty-bed volumes). DOM inhibited GAC-based H₂O₂ quenching via a pore-blocking effect, especially at high concentrations (10 mg/L), with the adsorbed DOM molecules being oxidized by the continuously generated ·OH; this further deteriorated the H₂O₂ quenching efficiency. In batch experiments, H₂O₂ could enhance DOM adsorption by GAC; however, in RSSCTs, it deteriorated DOM removal. This observation could be attributed to the different ·OH exposure in these two systems. It was also observed that aging with H₂O₂ and DOM altered the morphology, specific surface area, pore volume, and the surface functional groups of GAC, owing to the oxidation effect of H₂O₂ and ·OH on the GAC surface as well as the effect of DOM. Additionally, the changes in the content of persistent free radicals in the GAC samples were insignificant following different aging processes. This work contributes to enhancing understanding regarding the UV/H₂O₂-GAC filtration scheme, and promoting the application in drinking water treatment.