Dual-functional lignin-based hydrogels for sustained release of agrochemicals and heavy metal ion complexation

An effective way of improving the efficiency of agrochemicals and improving crop yield and quality is by slow or sustained release, which is conducive to environmental protection. Meanwhile, the excessive amount of heavy metal ions in soil can create toxicity in plants. Here, we prepared lignin-based dual-functional hydrogels containing conjugated agrochemical and heavy metal ligands through free-radical copolymerization. The content of the agrochemicals (including plant growth regulator 3-indoleacetic acid (IAC) and herbicide 2,4-dichlorophenoxyacetic acid (DCP)) in the hydrogels were tuned by changing the hydrogel composition. The conjugated agrochemicals could slowly release through the gradual cleavage of the ester bond. As a result of the release of the DCP herbicide, the growth of lettuce was effectively regulated, thus confirming the feasibility and effectiveness of this system in application. At the same time, due to the presence of metal chelating groups (such as COOH, phenolic OH, and tertiary amine) the hydrogels could act as adsorbents or stabilizers towards heavy metal ions for improving the soil remediation and preventing the adsorption of these toxic metals by plant roots. Specifically, Cu(II) and Pb(II) could be adsorbed >380 and 60 mg/g, respectively.