Engineering amorphous SnO₂ nanoparticles integrated into porous N-doped carbon matrix as high-performance anode for...

A facile in-situ preparation strategy is proposed to anchor amorphous SnO₂ nanoparticles into the porous N-doped carbon (NC) matrix to fabricate amorphous composite powders (am-SnO₂@p-NC), which feature the hierarchically interconnected and well interlaced porous configurations by employing polyvinylpyrrolidone as the soft template. The morphology regulation of the porous structure is precisely realized by adjusting the content of the template and the relationship between structural evolution and electrochemical performance of composite powders is accurately described to explore the optimal template dosage. The results indicate that the am-SnO₂@p-NC-50 % composite electrode can deliver the improved lithium storage capacity and cycling performance when the content of the template is controlled at 0.500 g, in which the initial discharge specific capacity is about 1557.6 mAh/g and the reversible value retains at 841.5 mAh/g after 100 cycles at 100 mA/g. Meanwhile, the discharge specific capacity of 869.8 mAh/g is exhibited for the am-SnO₂@p-NC-50 % composite electrode after 60 cycles when the current density is recovered from 2000 to 100 mA/g. Moreover, the Li⁺ ions diffusion coefficient up to about 5.5 × 10^-12 cm²/s is calculated from galvanostatic intermittent titration technique tests, which can be partly ascribed to the conductive NC substrate that provides the high electronic conductivity, and partly to the highly porous structure that shortens Li⁺ ions transfer pathways and guarantees the fast reaction kinetics. Therefore, the hierarchically porous engineering of carbon networks to confine amorphous transition metal oxide nanoparticles is of great significance in the development of high-performance anode materials for lithium-ion batteries.