Two-dimensional transition metal carbide (Ti_0.5V_0.5)₃C₂T_x MXene as high performance electrode for flexible...

MXenes have gained widespread interest in flexible supercapacitor due to their rich electrochemical activity and free-standing electrode structure. However, it has been a challenge to obtain an electrode with high (mass and volumetric) specific capacitance, high rate and long cycle life simultaneously. Herein, we have prepared a novel few-layer double transition metal carbide (Ti_0.5V_0.5)₃C₂T_x MXene. Multivalent V atoms with high electrochemical activity were constructed in stable M₃C₂-type MXene to obtain the (Ti_0.5V_0.5)₃C₂T_x electrode with excellent performance in flexible supercapacitors. The (Ti_0.5V_0.5)₃C₂T_x film has an excellent specific capacitance of 387F g^-1 (1625 mF cm^-3) at 1.0 A g^-1, and 267 F g^-1 (1121 mF cm^-3) even at a high current density of 20.0 A g^-1, demonstrating superior rate performance (69%). Moreover, the capacitance of the (Ti_0.5V_0.5)₃C₂T_x film remains stable during 100,000 cycles. The symmetric supercapacitor assembled using (Ti_0.5V_0.5)₃C₂T_x film has high energy and power densities, up to 5.6 Wh kg^-1 and 5210.3 W kg^-1. And the all-solid-state (Ti_0.5V_0.5)₃C₂T_x flexible SC maintains stable electrochemical performance after 200 bending cycles. This work shows the huge potential of (Ti_0.5V_0.5)₃C₂T_x in flexible supercapacitor, and provides a new idea for the design of high performance flexible electrodes.