Oxide-Metal Interaction Probed by Scanning Tunneling Microscope Manipulation of Cr₂O₇ Clusters on Au(111)

Interfacial interaction plays a crucial rule in catalysis over supported catalysts, and the catalyst-support interaction needs to be explored at microscopic scale. Here, we use the scanning tunneling microscope (STM) tip to manipulate Cr₂O₇ dinuclear clusters on Au(111) and find that the Cr₂O₇-Au interaction can be weakened by an electric field in the STM junction, facilitating rotation and translation of the individual clusters at the imaging temperature (78 K). Surface alloying with Cu makes the manipulation of the Cr₂O₇ clusters hard due to the enhanced Cr₂O₇-substrate interaction. Density functional theory calculations reveal that barrier for translation of a Cr₂O₇ cluster on the surface can be increased by surface alloying, influencing the tip manipulation. Our study demonstrates that the oxide-metal interfacial interaction can be probed by STM tip manipulation of supported oxide clusters, which provides a new method to investigate the interfacial interaction.