13% Single-Component Organic Solar Cells based on Double-Cable Conjugated Polymers with Pendent Y-Series Acceptors

Double-cable conjugated polymers with pendent electron acceptors, including fullerene, rylene diimides, and nonfused acceptors, have been developed for application in single-component organic solar cells (SCOSCs) with efficiencies approaching 10%. In this work, Y-series electron acceptors have been firstly incorporated into double-cable polymers in order to further improve the efficiencies of SCOSCs. A highly crystalline Y-series acceptor based on quinoxaline core and the random copolymerized strategy are used to optimize the ambipolar charge transport and the nanophase separation of the double-cable polymers. As a result, an efficiency of 13.02% is obtained in the random double-cable polymer, representing the highest performance in SCOSCs, while the regular double-cable polymer only provides a low efficiency of 2.75%. The significantly enhanced efficiencies are attributed to higher charge carrier mobilities, better ordering conjugated backbones and Y-series acceptors in random double-cable polymers.