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Updated: Aug 9, 2025

Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Free radicals promote electrocatalytic nitrogen oxidation
Zuochao Wang1, Jiao Liu1, Huan Zhao1
1State Key Laboratory of Eco-chemical Engineering, International Science and Technology Cooperation Base of Eco-chemical Engineering and Green Manufacturing, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology Qingdao 266042 P. R. China jplai@qust.edu.cn inorchemwl@126.com.
Abstract:
In this work, we introduce hydroxyl radicals into the electrocatalytic nitrogen oxidation reaction (NOR) for the first time. Cobalt tetroxide (Co3O4) acts not only as an electrocatalyst, but also as a nanozyme (in combination with hydrogen peroxide producing ˙OH), and can be used as a high-efficiency nitrogen oxidation reaction (NOR) electrocatalyst for environmental nitrate synthesis. Co3O4 + ˙OH shows an excellent nitrogen oxidation reaction (NOR) performance among Co3O4 catalysts in 0.1 M Na2SO4 solution. At an applied potential of 1.7 V vs. RHE, the HNO3 yield of Co3O4 + ˙OH reaches 89.35 μg h-1 mgcat -1, which is up to 7 times higher than that of Co3O4 (12.8 μg h-1 mgcat -1) and the corresponding FE is 20.4%. The TOF of Co3O4 + ˙OH at 1.7 V vs. RHE reaches 0.58 h-1, which is higher than that of Co3O4 (0.083 h-1), demonstrating that free radicals greatly enhance the intrinsic activity. Density functional theory (DFT) demonstrates that ˙OH not only can drive nitrogen adsorption, but also can decrease the energy barrier (rate-determining step) of N2 to N2OH*, thus producing great NOR activity.
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