Enhanced nitrate contribution to light extinction during haze pollution in Chengdu: Insights based on an improved...

In recent years, the annual mean concentration of PM_2.5 has decreased in Chengdu, China; however, atmospheric visibility has not improved accordingly. Low-visibility events occurred even when the PM_2.5 mass concentrations were below the national ambient air quality secondary standard (daily mean concentration, 75 μg/m³). In this study, the non-linear relationship between PM_2.5 and visibility was analyzed under different NO₃^- mass fractions in PM_2.5 based on 2-year field observation data. The results indicated that NO₃^- formation contributed to particulate pollution events and reduced atmospheric visibility. Multiple linear regression was used to propose a localized reconstruction equation for the light-scattering coefficient. According to the maximum likelihood estimation method and log-transformed residuals, the mass scattering coefficients (MSEs) of organic matter (OM), NH₄NO₃, and (NH₄)₂SO₄ in Chengdu were 7.42, 3.83, and 3.80, respectively. OM and NH₄NO₃ contributed to more than 50% of the light-extinction coefficient (b_ext). NH₄NO₃ was the main pollutant causing the substantial increase in b_ext. Chengdu has a high relative humidity (annual mean 70%), and under such conditions, the contribution of NH₄NO₃ to b_ext was considerably enhanced through hygroscopic growth and heterogeneous reactions. This study estimated the localized MSEs of OM, NH₄NO₃, and (NH₄)₂SO₄ in Chengdu and emphasized that effective control measures to reduce nitrate and its precursors could simultaneously ameliorate air quality and visibility in humid regions with poor atmospheric visibility.