Review of air-water interface adsorption and reactions between trace gaseous organic and oxidant compounds

The surface chemistry of the atmospheric aerosol through homogeneous and heterogeneous catalytic reactions in the bulk water and the air-water surface is reviewed. Water plays a critical role as a substrate or an actual reactant in atmospheric reactions. The atmospheric aerosol differs in shape and surface area. Many gaseous reactive species and oxidants react at the air-water surface. Different thermodynamic methods to estimate partitioning coefficients are explored. The Gibbs free energy is reduced when reactant gaseous species react with oxidant at the air-water surface; this phenomenon is explained using examples. Langmuir-Hinshelwood reaction mechanism to quantify the heterogeneous reaction rate at the air-water interface is discussed. Critical comparisons of various sampling techniques used to analyze adsorption and reaction at the water surface are presented. The heterogeneous reaction rate at the air-water surface is significantly higher than in the bulk water phase due to a cage effect, higher rate of reactions, and lower Gibbs free energy of adsorption.