Hydroxycinnamic acid derivatives for UV-selective and visibly transparent dye-sensitized solar cells

Naturally abundant dyes are very attractive for the development of dye-sensitized solar cells (DSSCs). Hydroxycinnamic acid derivatives, such as caffeic acid (CA), ferulic acid (FA), and p-coumaric acid (PA), were considered for the selective harvesting of ultraviolet A (UVA) (315-400 nm) photons. Their spectroscopic and electrochemical properties were investigated both theoretically and experimentally. They were further successfully adopted as photosensitizers in UV-selective and visibly transparent DSSCs, which exhibited a power conversion efficiency of 0.22-0.38% under AM (air mass) 1.5G (global) illumination (100 mW/cm²) and 3.40-3.62% under UVA irradiation (365 nm, 115.22 mW/cm²), with a corresponding visible light transmittance (VLT) of 49.07-43.72% and a general color rendering index (R_a) of 93-90.