Enhanced Coloration Time of Electrochromic Device Using Integrated WO₃@PEO Electrodes for Wearable Devices

Electrochromic technologies that exhibit low power consumption have been spotlighted recently. In particular, with the recent increase in demand for paper-like panel displays, faster coloration time has been focused on in researching electrochromic devices. Tungsten trioxide (WO₃) has been widely used as an electrochromic material that exhibits excellent electrochromic performance with high thermal and mechanical stability. However, in a solid film-type WO₃ layer, the coloration time was long due to its limited surface area and long diffusion paths of lithium ions (Li-ions). In this study, we attempted to fabricate a fibrous structure of WO₃@poly(ethylene oxide) (PEO) composites through electrospinning. The fibrous and porous layer showed a faster coloration time due to a short Li-ion diffusion path. Additionally, PEO in fibers supports Li-ions being quickly transported into the WO₃ particles through their high ionic conductivity. The optimized WO₃@PEO fibrous structure showed 61.3 cm²/C of high coloration efficiency, 1.6s fast coloration time, and good cycle stability. Lastly, the electrochromic device was successfully fabricated on fabric using gel electrolytes and a conductive knitted fabric as a substrate and showed a comparable color change through a voltage change from -2.5 V to 1.5 V.