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Surface-Modified In2O3 for High-Throughput Screening of Volatile Gas Sensors in Diesel and Gasoline
Deqi Zhang1,2, Shenghui Guo1,2, Jiyun Gao2
1State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China.
Abstract:
In this paper, with the help of the method of composite materials science, parallel synthesis and high-throughput screening were used to prepare gas sensors with different molar ratios of rare earths and precious metals modified In2O3, which could be used to monitor and warn the early leakage of gasoline and diesel. Through high-throughput screening, it is found that the effect of rare earth metal modification on gas sensitivity improvement is better than other metals, especially 0.5 mol% Gd modified In2O3 (Gd0.5In) gas sensor has a high response to 100 ppm gasoline (R/R = 6.1) and diesel (R/R = 5) volatiles at 250 °C. Compared with the existing literature, the sensor has low detection concentration and suitable stability. This is mainly due to the alteration of surface chemisorption oxygen caused by the catalysis and modification of rare earth itself.
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