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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
18.5K
Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

1.2K
Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
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Temperature Dependent Deformation01:12

Temperature Dependent Deformation

177
In a nonhomogeneous rod made up of steel and brass, restrained at both ends and subjected to a temperature change, several steps are involved in calculating the stress and compressive load. Due to the problem's static indeterminacy, one end support is disconnected, allowing the rod to experience the temperature change freely. Next, an unknown force is applied at the free end, triggering deformations in the rod's steel and brass portions. These deformations are then calculated and added...
177
Theory of Metallic Conduction01:17

Theory of Metallic Conduction

1.4K
The conduction of free electrons inside a conductor is best described by quantum mechanics. However, a classical model makes predictions close to the results of quantum mechanics. It is called the theory of metallic conduction.
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
1.4K
Bonding in Metals02:32

Bonding in Metals

47.6K
Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
47.6K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

17.3K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
17.3K

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Updated: Aug 9, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
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Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses

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Rapid Multicomponent Alloy Solidification with Allowance for the Local Nonequilibrium and Cross-Diffusion Effects.

Sergey L Sobolev1, Mikhail G Tokmachev2, Yuri R Kolobov1

  • 1Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432 Chernogolovka, Russia.

Materials (Basel, Switzerland)
|February 25, 2023
PubMed
Summary

This study models femtosecond laser melting and re-solidification of metal alloys under nonequilibrium conditions. It identifies three re-solidification regimes that control final material composition for additive manufacturing.

Keywords:
mathematical modelingmetallic alloysmulti-component diffusionnumerical calculationsternary systems

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Area of Science:

  • Materials Science
  • Metallurgy
  • Computational Modeling

Background:

  • Additive manufacturing (AM) technologies are rapidly advancing.
  • Ultrashort pulse laser melting induces highly nonequilibrium re-solidification conditions.
  • Classical diffusion models (Fick's law) are insufficient for these nonequilibrium scenarios.

Purpose of the Study:

  • To develop a mathematical model for re-solidification of multicomponent metal alloys after femtosecond laser surface melting.
  • To investigate the influence of hyperbolic diffusion and solute interactions on re-solidification.
  • To identify distinct re-solidification regimes and their impact on material properties.

Main Methods:

  • Development of a mathematical model incorporating hyperbolic diffusion (non-Fickian).
  • Inclusion of diffusive interactions between different solutes (off-diagonal diffusion matrix terms).
  • Numerical simulations to analyze re-solidification dynamics and identify regimes.

Main Results:

  • Three primary re-solidification regimes were identified: diffusion-controlled with partition, partly diffusion-controlled with weak partition, and diffusionless/partitionless.
  • The identified regime significantly influences the final composition of the re-solidified alloy.
  • The model accounts for nonequilibrium solute diffusion and inter-solute interactions.

Conclusions:

  • The re-solidification regime is a critical factor in determining the final composition and properties of additively manufactured materials.
  • This model provides a tool for evaluating re-solidification strategies.
  • The findings can guide the optimization of AM processing parameters and alloy design for desired material properties.