Ozone Diffusion through a Hollow Fiber Membrane Contactor for Pharmaceuticals Removal and Bromate Minimization

Recently, ozonation has been advocated as a solution to tackle emerging contaminants. Hollow fiber membrane contactors (HFMC) have a lower residual ozone concentration than bubble reactors that could limit the formation of potential ozonation by-products, especially bromates that are regulated in drinking water. The aim of this study was to evaluate ozonation with HFMC for pharmaceutical abatement and bromate minimization compared to bubble columns in wastewater. A HFMC, composed of 65 polytetrafluoroethylene hollow fibers with a 0.45 mm/0.87 mm inner/external diameter and a 0.107 m² exchange surface, was used for the ozonation of real-treated wastewater spiked with 2 µM of p-chlorobenzoic acid (p-CBA) and 3 mg.L^-1 of bromide. p-CBA was tracked to monitor the production of strongly-oxidant hydroxyl radicals from the decomposition of the molecular ozone. At 100% p-CBA abatement, 1600 µg.L^-1 of bromate was formed with the HFMC, whereas 3486 µg.L^-1 was formed with the bubble column. These results demonstrate that HFMC can produce a significant amount of hydroxyl radicals while limiting bromate formation in real-treated wastewater. The test water was also spiked with carbamazepine and sulfamethoxazole to evaluate the abatement efficiency of the process. Short contact times (approximately 2s) achieved high rates of pharmaceuticals removal without bromate formation.