Pd/Pt-Bimetallic-Nanoparticle-Doped In₂O₃ Hollow Microspheres for Rapid and Sensitive H₂S Sensing at Low Temperature

H₂S is a poisonous gas that is widespread in nature and human activities. Its rapid and sensitive detection is essential to prevent it from damaging health. Herein, we report Pd- and Pt-bimetallic-nanoparticle-doped In₂O₃ hollow microspheres that are synthesized using solvothermal and in situ reduction methods for H₂S detection. The structure of as-synthesized 1 at% Pd/Pt-In₂O₃ comprises porous hollow microspheres assembled from In₂O₃ nanosheets with Pd and Pt bimetallic nanoparticles loaded on its surface. The response of 1 at% Pd/Pt-In₂O₃ to 5 ppm H₂S is 140 (70 times that of pure In₂O₃), and the response time is 3 s at a low temperature of 50 °C. In addition, it can detect trace H₂S (as low as 50 ppb) and has superior selectivity and an excellent anti-interference ability. These outstanding gas-sensing performances of 1 at% Pd/Pt-In₂O₃ are attributed to the chemical sensitization of Pt, the electronic sensitization of Pd, and the synergistic effect between them. This work supplements the research of In₂O₃-based H₂S sensors and proves that Pd- and Pt-bimetallic-doped In₂O₃ can be applied in the detection of H₂S.