Self-supporting NiMo-Fe-P nanowire arrays as bifunctional catalysts for efficient overall water splitting

Developing efficient bifunctional hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalysts is beneficial for simplifying the design of electrolytic cells and reducing the cost of device manufacturing. Herein, a metal phosphide nanoarray (NiMo-Fe-P) electrocatalyst was designed by in situ ion exchange and low-temperature phosphating to promote overall water splitting in 1 M KOH. NiMo-Fe-P demonstrates superb HER and OER activities as reflected by the low overpotentials of 73.1 mV and 215.2 mV, respectively, at a current density of 10 mA cm^-2. The addition of Fe changes the electronic structure of Ni, which is conducive to the chemisorption of oxygen-containing intermediates and reduces the energy barrier for water decomposition. Besides, the metal phosphide not only acts as the active site of the HER, but also improves the conductivity of the catalyst. Furthermore, nanowire arrays and the small particles generated on their surfaces provide a high electrochemical active surface area (ECSA), which was beneficial for the exposure of active sites. Attributed to these advantages, the cell voltage of the water electrolyzer constructed with NiMo-Fe-P as both the cathode and anode is only 1.526 V at 10 mA cm^-2, and it maintains excellent stability for 100 h with near negligible changes in potential.