Determination of trace potassium permanganate in tap water by solid phase extraction combined with spectrophotometry

A simple solid phase extraction (SPE) coupled with spectrophotometric method was developed for determination of trace permanganate (MnO₄ ^-) in water. Commercial reagent polyamined-6 powder was used as SPE stationary phase to retain MnO₄ ^- which is based on the fact that MnO₄ ^- can be adsorbed on polyamide 6 (PA-6) sorbent as water samples flow through the SPE cartridge. 3,3',5,5'-tetramethylbenzidine (TMB) were used both as eluent solution and chromogenic agent to convert the adsorbed MnO₄ ^- into Mn²⁺ and generate blue oxidized product with high molar absorptivity. Quantification of MnO₄ ^- could be obtained by spectrophotometric detection of the resulting solution flow out of the SPE cartridge. The extraction and detection variables was optimized to maximize the absorbance of the TMB oxidized product. Under optimized conditions, this method provided linear dynamic ranges of 0.01-1 μmol L^-1 for MnO₄ ^- with preconcentration of 100 mL water sample. The limits of detection (3S_b/m) of this method in deionized water were calculated to be 5.1 nM, and the relative standard deviations were determined to be 3.2% (C = 0.1 μmol L^-1, n = 5). This method has been applied to the determination of MnO₄ ^- in spiked tap waters and satisfactory recovery was obtained.