Refining the Spectroscopic Detection Technique: A Pivot in the Electrochemical Ammonia Synthesis

Ammonia has been recognized as the future fuel because of its immense advantages over liquid hydrogen. The research trend nowadays is mostly inclined toward the electrochemical ammonia synthesis since it offers a sustainable method of green ammonia production. The indophenol blue method is one of the largely used colorimetric techniques to detect ammonia spectroscopically but lacks a proper experimental protocol. The unresolved speculations related to this method concerning stability of dye, sequence of mixing of reagents, importance of pH in the dye formation, or sensitivity of the method to interferants need vigorous experimental verification and a legitimate protocol has to be set up for a reliable and reproducible data. This work thus aims to unveil the artefacts of this method and explore the mechanisms involved such that it becomes easy for a newcomer as well as existing researchers in the field to understand the requirement of rigorous optimizations in this technique.