Effect of oxygen vacancy and highly dispersed MnO_x on soot combustion in cerium manganese catalyst

Cerium manganese bimetallic catalysts have become the focus of current research because of their excellent catalytic performance for soot combustion. Two series of cerium manganese catalysts (Na-free catalysts and Na-containing catalysts) were prepared by coprecipitation method and characterized using XRD, N₂ adsorption-desorption, SEM, Raman, XPS, H₂-TPR, O₂-TPD, Soot-TPR-MS and in situ IR. The effects of abundant oxygen vacancies and surface highly dispersed MnO_x on soot catalytic combustion of cerium manganese catalysts prepared by different precipitants were analyzed. The activity test results show that the active oxygen species released by a large number of oxygen vacancies in the cerium manganese catalyst are more favorable to the soot catalytic combustion than MnO_x which is highly dispersed on the surface of the catalyst and has good redox performance at low temperature. Because the catalytic effect of MnO_x on the surface of Na-free catalysts is more dependent on the contact condition between the catalyst and the soot, this phenomenon can be observed more easily under the loose contact condition than under the tight contact condition. The activity cycle test results show that these two series of catalysts show good stability and repeated use will hardly cause any deactivation of the catalysts.