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Lei Tian1, Jing Liang1, Yingjie Gao1

  • 1Key Laboratory of Synthetic and Natural Functional Molecular Chemistry, College of Chemistry & Materials Science, Northwest University, Xi'an 710069, P. R. China. tianl@nwu.edu.cn.

Physical Chemistry Chemical Physics : PCCP
|March 1, 2023
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Controlled-Potential Coulometry: Electrolytic Methods01:17

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Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential is precisely regulated using a potentiostat. Platinum working electrodes are utilized for positive potentials, while mercury pool electrodes are favored for extremely negative potentials. The platinum counter electrode is separated from the analyte using a membrane or salt bridge to avoid interference in the analysis.
The chosen potential ensures...