Effecting pattern study of SO₂ on Hg⁰ removal over α-MnO₂ in-situ supported magnetic composite

α-MnO₂ was in-situ supported onto silica coated magnetite nanoparticles (MagS-Mn) to study the adsorption and oxidation of Hg⁰ as well as the effecting patterns of SO₂ and O₂ on Hg⁰ removal. MagS-Mn showed Hg⁰ removal capacity of 1122.6 μg/g at 150 °C with the presence of SO₂. Hg⁰ adsorption and oxidation efficiencies were 2.4% and 90.6%, respectively. Hg⁰ removal capability deteriorated at elevated temperatures. Surface oxygen and manganese chemistry analysis indicated that SO₂ inhibited the Hg⁰ removal through consumption of adsorbed oxygen and reduction of high valence manganese. This inhibiting effect was observed to be counteracted by O₂ at lower temperatures. O₂ tended to compete with SO₂ for active sites and further create additional adsorbed oxygen sites for Hg⁰ surface reaction via surface dissociative adsorption rather than replenish the active sites consumed by SO₂. The high valence manganese was also preserved by O₂ which was essential to Hg⁰ oxidation. The intervention of O₂ in the inhibition of SO₂ on Hg⁰ removal was weakened at temperatures higher than 250 °C. Aa a result, Hg⁰ tends to be catalytic oxidized in the condition of low reaction temperatures and with the presence of O₂ over α-MnO₂ oriented composites.