Enhanced nitrate removal using in situ reactive zone with reduced graphene oxide supported nanoscale zero-valent iron

Nitrate pollution in groundwater is becoming more serious, which is harmful to human health. The reduced graphene oxide supported nanoscale zero-valent iron (nZVI/rGO) composite prepared in this paper can effectively remove nitrate in groundwater. In situ remediation of nitrate-contaminated aquifer was also studied. The results showed that NH₄⁺-N was the main product of NO₃^--N reduction, and N₂ and NH₃ were also produced. When the dosage of rGO/nZVI was more than 0.2 g/L, there was no accumulation of intermediate NO₂^--N during the reaction process. NO₃^--N was removed by rGO/nZVI mainly through physical adsorption and reduction process with the maximum adsorbing ability of 37.44 mg NO₃^--N/g. After the slurry of rGO/nZVI was injected into the aquifer, a stable reaction zone could be formed. NO₃^--N could be removed continuously within 96 h at the simulated tank, and NH₄⁺-N and NO₂^--N were as the main reduction products. Moreover, the concentration of TFe near the injection well increased rapidly after rGO/nZVI injection, and could be detected at the downstream end, indicating that the reaction range was large enough for NO₃^--N removal.