Immobilization of Cd by mercapto-palygorskite in typical calcareous and acidic soil aggregates: Performance and...

The microscale spatial heterogeneity and complexity of soil aggregates affect the properties and distribution of heavy metals (HMs). It has been confirmed that amendments can alter the distribution of Cd in soil aggregates. However, whether the Cd immobilization effect of amendments varies across soil aggregate levels remains unknown. In this study, soil classification and culture experiments were combined to explore the effects of mercapto-palygorskite (MEP) on Cd immobilization in soil aggregates of different particle sizes. The results showed that a 0.05-0.2% MEP application decreased soil available Cd by 53.8-71.62% and 23.49-36.71% in calcareous and acidic soils, respectively. The Cd immobilization efficiency of MEP in calcareous soil aggregates was in the following order: micro-aggregates (66.42-80.19%) > bulk soil (53.78-71.62%) > macro-aggregates (44.00-67.51%), while the efficiency in acidic soil aggregates was inconsistent. In MEP-treated calcareous soil, the percentage change in Cd speciation in micro-aggregates were higher than that in macro-aggregates, whereas there was no significant difference in Cd speciation between the four acidic soil aggregates. Mercapto-palygorskite addition in micro-aggregates of calcareous soil increased the available Fe and Mn concentrations by 20.98-47.10% and 17.98-32.66%, respectively. Mercapto-palygorskite had no effect on soil pH, EC, CEC, and DOC values, while the difference in soil properties between the four particle sizes was the main influencing factor of MEP treatments on Cd in calcareous soil. The effects of MEP on HMs varied across soil aggregates and soil types, but had strong specificity and selectivity for Cd immobilization. This study illustrates the influence of soil aggregates on Cd immobilization using MEP, which can be used to guide the remediation of Cd-contaminated calcareous and acidic soils.