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Surface modification of gold by carbazole dendrimers for improved carbon dioxide electroreduction
Sota Yoshida1, Masaki Sampei1, Naoto Todoroki1,2
1Graduate School of Environmental Studies, Tohoku University, 6-2-2 Aramakiaza-Aoba Aoba-ku, Sendai 980-8579, Japan. naoto.todoroki.b1@tohoku.ac.jp.
Abstract:
Four types of carbazole dendrimers were applied as modification molecules of Au surfaces to improve carbon dioxide electroreduction. The reduction properties depended on the molecular structures: the highest activity and selectivity to CO was achieved by 9-phenylcarbazole, probably caused by the charge transfer from the molecule to Au.

