Peroxymonosulfate activation by graphene oxide-supported 3D-MoS₂/FeCo₂O₄ sponge for highly efficient organic...

To address conventional powder catalysts' recovery and aggregation issues that greatly restrain their practical application, a recoverable graphene oxide (GO)-supported 3D-MoS₂/FeCo₂O₄ sponge (SFCMG) was developed through a simple impregnation pyrolysis method. SFCMG can efficiently activate peroxymonosulfate (PMS) to produce reactive species for rapid degradation of rhodamine B (RhB), with 95.0% and 100% of RhB being removed within 2 min and 10 min, respectively. The presence of GO enhances the electron transfer performance of the sponge, and the three-dimensional melamine sponge serves as a substrate to provide a highly dispersed carrier for FeCo₂O₄ and MoS₂/GO hybrid sheets. SFCMG exhibits a synergistic catalytic effect of Fe and Co, and facilitates the redox cycles of Fe(III)/Fe(II) and Co(III)/Co(II) by MoS₂ co-catalysis, which enhances its catalytic activity. Electron paramagnetic resonance results demonstrate that SO₄^•-, ·O₂^- and ¹O₂ are all involved in SFCMG/PMS system, and ¹O₂ played a prominent role in RhB degradation. The system has good resistance to anions (Cl^-, SO₄^2-, and H₂PO₄^-) and humic acid and excellent performance for many typical contaminants degradation. Additionally, it works efficiently over a wide pH range (3-9) and possesses high stability and reusability with the metal leaching far below the safety standards. The present study extends the practical application of metal co-catalysis and offers a promising Fenton-like catalyst for the treatment of organic wastewater.