Nanoporous hydrogel absorbent based on salep: Swelling behavior and methyl orange adsorption capacity

This study used the gas-blowing method to develop a nanoporous hydrogel using poly (3-sulfopropyl acrylate-co-acrylic acid-co-acrylamide) grafted onto salep. The synthesis of the nanoporous hydrogel was optimized by various parameters for maximum swelling capacity. The nanoporous hydrogel was characterized using FT-IR, TGA, XRD, TEM, and SEM analyses. Images from SEM showed numerous pores and channels in the hydrogel with an average size of about 80 nm, forming a honeycomb-like shape. The change in surface charge was investigated by zeta potential and revealed that the surface charge of the hydrogel ranged from 20 mV at acidic conditions to -25 mV at basic conditions. The swelling behavior of optimum superabsorbent hydrogel was determined under different environmental conditions, such as different pH values, ionic strengths of the environment, and solvents. In addition, the swelling kinetics and the absorbance under loading of the hydrogel sample in different environments were investigated. Moreover, Methyl Orange (MO) dye was removed from aqueous solutions using the nanoporous hydrogel as an adsorbent. The adsorption behavior of the hydrogel was examined under various conditions, and the adsorption capacity of the hydrogel was found tobe 400 mg g^-1. The maximum water uptake was obtained under the following conditions: Salep weight = 0.01 g, AA = 60 μL, MBA = 300 μL, APS = 60 μL, TEMED = 90 μL, AAm = 600 μL, and SPAK = 90 μL. Lastly, the adsorption kinetics was studied by employing pseudo-first-order, pseudo-second-order, and intra-particle diffusion models.