Utilizing CO₂ as a Reactant for C₃ Oxygenate Production via Tandem Reactions

One possible solution to closing the loop on carbon emissions is using CO₂ as the carbon source to generate high-value, multicarbon products. In this Perspective, we describe four tandem reaction strategies for converting CO₂ into C₃ oxygenated hydrocarbon products (i.e., propanal and 1-propanol), using either ethane or water as the hydrogen source: (1) thermocatalytic CO₂-assisted dehydrogenation and reforming of ethane to ethylene, CO, and H₂, followed by heterogeneous hydroformylation, (2) one-pot conversion of CO₂ and ethane using plasma-activated reactions in combination with thermocatalysis, (3) electrochemical CO₂ reduction to ethylene, CO, and H₂, followed by thermocatalytic hydroformylation, and (4) electrochemical CO₂ reduction to CO, followed by electrochemical CO reduction to C₃ oxygenates. We discuss the proof-of-concept results and key challenges for each tandem scheme, and we conduct a comparative analysis of the energy costs and prospects for net CO₂ reduction. The use of tandem reaction systems can provide an alternative approach to traditional catalytic processes, and these concepts can be further extended to other chemical reactions and products, thereby opening new opportunities for innovative CO₂ utilization technologies.