A robust and porous titanium metal-organic framework for gas adsorption, CO₂ capture and conversion

A robust and porous titanium metal-organic framework (Ti-MOF; LCU-402) has been hydrothermally synthesized through combining a tetranuclear Ti₂Ca₂(μ₃-O)₂(μ₂-H₂O)_1.3(H₂O)₄(O₂C-)₈ cluster and a tritopic 1,3,5-benzene(tris)benzoic (BTB) ligand. LCU-402 shows remarkable stability and permanent porosity for CO₂, CH₄, C₂H₂, C₂H₄, and C₂H₆ gas adsorption. Moreover, LCU-402 as a heterogeneous catalyst can smoothly convert CO₂ under a simulated flue atmosphere into organic carbonate molecules by cycloaddition reactions of CO₂ and epoxides, indicating that LCU-402 might be a promising catalyst candidate in practical applications. We are confident that the identification of a persistent titanium-oxo building unit would accelerate the development of new porous Ti-MOF materials.