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Colloids03:22

Colloids

17.7K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Surface Tension of Fluid01:22

Surface Tension of Fluid

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Surface tension is a fundamental property of fluids, occurring at the boundary between a liquid and a gas or between two immiscible liquids. This phenomenon arises from the cohesive forces between molecules at the fluid's surface, creating an effect similar to a stretched elastic membrane. Inside each fluid, molecules are equally attracted in all directions by neighboring molecules, but surface molecules experience a net inward force, resulting in surface tension.
Surface tension varies...
378
Molecular Weight of Step-Growth Polymers01:08

Molecular Weight of Step-Growth Polymers

2.3K
Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
The extent of the...
2.3K
Colloids and Suspensions01:17

Colloids and Suspensions

1.9K
Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
1.9K
Surface Tension and Surface Energy01:16

Surface Tension and Surface Energy

1.5K
When a paint brush is immersed in water, the bristles wave freely inside the water. When it is taken out, the bristles stick together. The reason behind this effect is surface tension.
Consider a beaker filled with liquid. The bulk molecules in the liquid experience equal attractive forces on all sides with the surrounding molecules. However, the surface molecules experience a net attractive force downward due to the bulk molecules. The surface of the liquid behaves like a stretched membrane,...
1.5K
Enthalpy of Solution02:39

Enthalpy of Solution

25.0K
There are two criteria that favor, but do not guarantee, the spontaneous formation of a solution:
25.0K

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On the role of surfactants in emulsions and foams.

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Related Experiment Video

Updated: Aug 7, 2025

Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown
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Real-Time Force Measurement Between Emulsion Droplets During Enzymatic Breakdown

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Recent Advances on Emulsion and Foam Stability.

Dominique Langevin1

  • 1Laboratoire de Physique des Solides, UMR CNRS 8502, Université Paris Saclay, 91405 Orsay, France.

Langmuir : the ACS Journal of Surfaces and Colloids
|March 7, 2023
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Summary

This paper explores open problems in emulsion and foam stability, focusing on surfactant-stabilized dispersions. Key destabilization processes like coalescence and Ostwald ripening are analyzed, showing progress but highlighting remaining challenges.

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Area of Science:

  • Colloid and Surface Science
  • Fluid Dynamics
  • Materials Science

Background:

  • Emulsions and foams are ubiquitous in nature and industry.
  • Their stability is crucial for product performance and shelf-life.
  • Surfactant stabilization is a fundamental aspect of dispersion science.

Purpose of the Study:

  • To identify and discuss key open problems in emulsion and foam stability.
  • To analyze major destabilization mechanisms in surfactant-stabilized systems.
  • To provide a perspective on the current state and future directions in the field.

Main Methods:

  • Theoretical analysis of destabilization processes.
  • Review of recent advancements in understanding stability.
  • Focus on Newtonian fluids with micellar presence.

Main Results:

  • Identified gravity-induced evolution, Ostwald ripening, and coalescence as primary destabilization pathways.
  • Highlighted progress in understanding these mechanisms.
  • Confirmed that significant challenges remain in predicting and controlling stability.

Conclusions:

  • Despite recent breakthroughs, the fundamental understanding of emulsion and foam stability requires further investigation.
  • Addressing the outlined open problems is essential for advancing colloid and surface science.
  • Continued research is needed to develop more robust and predictable stabilization strategies.