Adsorption of Pb(II) from wastewater using a red mud modified rice-straw biochar: Influencing factors and reusability

Efficient environmental remediation of toxic chemicals using effective sorbents has received considerable attention recently. For the present study, the synthesis of a red mud/biochar (RM/BC) composite was performed from rice straw with the aim of achieving Pb(II) removal from wastewater. Characterization was performed by using X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), Zeta potential analysis, elemental mapping, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Results showed that RM/BC had higher specific surface area (S_BET = 75.37 m² g^-1) than raw biochar (S_BET = 35.38 m² g^-1). The Pb(II) removal capacity (q_e) of RM/BC was 426.84 mg g^-1 at pH 5.0, and the adsorption data well fitted pseudo second order kinetics (R² = 0.93 and R² = 0.98), as well as the Langmuir isotherm model (R² = 0.97 and R² = 0.98) for both BC and RM/BC. Pb(II) removal was slightly hindered with the increasing strength of co-existing cations (Na⁺, Cu²⁺, Fe³⁺, Ni²⁺, Cd²⁺). The increase in temperatures (298 K, 308 K, 318 K) favored Pb(II) removal by RM/BC. Thermodynamic study indicated that Pb(II) adsorption onto BC and RM/BC was spontaneous and primarily governed by chemisorption and surface complexation. A regeneration study revealed the high reusability (>90%) and acceptable stability of RM/BC even after five successive cycles. These findings indicate that RM/BC evidenced special combined characteristics of red mud and biochar, hence its use for Pb removal from wastewater offers a green and environmentally sustainable approach fitting the "waste treating waste" concept.