Near-Infrared Light Driven ZnIn₂S₄-Based Photocatalysts for Environmental and Energy Applications: Progress and...

Zinc indium sulfide (ZnIn₂S₄), as a significant visible-light-responsive photocatalyst, has become a research hotspot to tackle energy demand and environmental issues owing to its excellent properties of high stability, easy fabrication, and remarkable catalytic activity. However, its drawbacks, including low utilization of solar light and fast photoinduced charge carriers, limit its applications. Promoting the response for near-infrared (NIR) light (~52% solar light) of ZnIn₂S₄-based photocatalysts is the primary challenge to overcome. In this review, various modulation strategies of ZnIn₂S₄ have been described, which include hybrid with narrow optical gap materials, bandgap engineering, up-conversion materials, and surface plasmon materials for enhanced NIR photocatalytic performance in the applications of hydrogen evolution, pollutants purification, and CO₂ reduction. In addition, the synthesis methods and mechanisms of NIR light-driven ZnIn₂S₄-based photocatalysts are summarized. Finally, this review presents perspectives for future development of efficient NIR photon conversion of ZnIn₂S₄-based photocatalysts.