Interfacial engineering of Ti₃C₂ MXene/CdIn₂S₄ Schottky heterojunctions for boosting visible-light H₂ evolution and...

Developing efficient heterojunction photocatalysts that have a high charge carrier separation rate and improved light-harvesting capacity is a crucial step in solving energy crisis and reducing environmental pollution. Herein, we synthesized few-layered Ti₃C₂ MXene sheets (MXs) by a manual shaking process, and combined with CdIn₂S₄ (CIS) to construct novel Ti₃C₂ MXene/CdIn₂S₄ (MXCIS) Schottky heterojunction through a solvothermal method. The strong interface between two-dimensional (2D) Ti₃C₂ MXene and 2D CIS nanoplates led to enhanced light-harvesting capacity and promoted charge separation rate. Additionally, the presence of S vacancies on the MXCIS surface helped to trap free electrons. The optimal sample, 5-MXCIS (with 5 wt% MXs loading), exhibited outstanding performance for photocatalytic hydrogen (H₂) evolution and Cr(VI) reduction under visible light due to the synergistic effect of enhanced light-harvesting capacity and charge separation rate. The charge transfer kinetics was thoroughly studied using multiple techniques. The reactive species of ^•O₂^-, ^•OH and h⁺ were generated in 5-MXCIS system, and e^- and ^•O₂^- radicals were found to be the main contributors to Cr(VI) photoreduction. Based on the characterization results, a possible photocatalytic mechanism for H₂ evolution and Cr(VI) reduction was proposed. On the whole, this work provides new insights into the design of 2D/2D MXene-based Schottky heterojunction photocatalysts for boosting photocatalytic efficiency.